Product ID:ACE ANTIFREEZE & COOLANT
MSDS Date:03/15/1995
FSC:6850
NIIN:00N068089
MSDS Number: CDTLD

OLD WORLD INDUSTRIES INC

4065 COMMERCIAL AVE
NORTHBROOK, IL 60062
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 708-559-2000

Preparer: MICHAEL REED

Cage: 0U3B1

OLD WORLD INDUSTRIES INC

NORTHBROOK, IL 60062-1851 US

Telephone: 847-559-2173

Cage: 0U3B1

(ORAL, RAT) 5240

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 90-95%

OSHA PEL N/K

ACGIH TLV: 50 PPM, VAPOR, C

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

DIETHYLENE GLYCOL

CAS: 111-46-6

RTECS: ID5950000

Fraction By Weight: 0-5%

OSHA PEL N/K

ACGIH TLV: N/K

POTASSIUM PHOSPHATE; DIBASIC; (DI POTASSIUM PHOSPHATE)

CAS: 7758-11-4

Fraction By Weight: 1-2%

OSHA PEL N/K

ACGIH TLV: N/K

NOT LIKELY TO CAUSE INJURY BUT SWALLOWING

RTECS: 9999999ZZ

AT ROOM TEMP, EXPOS TO VAPS MINIMAL DUE

RTECS: 9999999ZZ

LEVELS SUFFICIENT TO CAUSE ADVERSE EFTS. SYSTEMIC

RTECS: 9999999ZZ

CNS EFTS,

RTECS: 9999999ZZ

ANIMALS INCL FORMATION OF BLADDER STONES AFTER RPTD

RTECS: 9999999ZZ

DEATH IN BURN PATIENTS SUGGEST ETHYLENE GLYCOL MAY

RTECS: 9999999ZZ

THIS MATL MAY NOT BE APPROP IN SEV BURNED

RTECS: 9999999ZZ

HAS CAUSED BIRTH DEFECTS IN LAB ANIMALS ONLY AT

RTECS: 9999999ZZ

ANIMALS EXCEPT AT VERY HIGH DOSES.

RTECS: 9999999ZZ

REMOVE TO FRESH AIR & CALL EMER MED CARE.

RTECS: 9999999ZZ

IF SWALLOWED, GIVE 2 GLASSES OF

RTECS: 9999999ZZ

PRESSING FINGER DOWN THROAT. SM AMTS ENTERING MOUTH

RTECS: 9999999ZZ

CHILDREN AWAY FROM SPILL SITE. PVC-COATED RUB

RTECS: 9999999ZZ

CLEANUP OF SPILL SITE. DO NOT DUMP USED

RTECS: 9999999ZZ

OTHER POS PRESS MODE IN COMBINATION W/AUXILIARY

RTECS: 9999999ZZ

ANY NIOSH APPRVD AIR-PURIFYING FULL

RTECS: 9999999ZZ

BACK-MOUNTED ORGANIC VAP CANISTER OR ANY APPROP

RTECS: 9999999ZZ

NEOPRENE; NITRILE; POLYVINYL ALCOHOL; NATURAL

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) 6,000-13,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE SLIGHT TRANSIENT IRRIT.
CORNEAL INJURY IS UNLIKELY. VAPS/MISTS MAY CAUSE IRRIT.
SKIN:PRLNGD/RPTD EXPOS IS NOT LIKELY TO CAUSE SIGNIFICANT IRRIT.
SINGLE PRLNGD EXPOS NOT LIKELY TO RSLT IN ABSORPTION THRU SKIN IN
HARMFUL AMTS. RPTD SKIN EXPOS MAY RSLT IN ABSORPTION OF HARMFUL
AMTS. MASSIVE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CNTCT W/DAMAGED SKIN OR MATL
SUFFICIENTLY HOT TO BURN SKIN MAY RSLT IN ABSORPTION OF POTNTL
LETHAL AMTS. INGEST:SINGLE DOSE ORAL TOX IS CONSIDERED TO BE MOD.
EXCESS EXPOS MAY CAUSE CNS EFTS, CARDIOPULM EFTS (METABOLIC
ACIDOSIS) & KIDNEY FAILURE. SM AMTS SWALLOWED INCIDENTAL TO NORM
HNDLG OPERATIONS ARE (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:ENSURE MD HAS ACCESS TO MSDS. EYE:IMMED FLUSH W/LG AMTS OF
WATER FOR AT LST 15 MIN, LIFTING LOWER & UPPER LIDS. GET MED ATTN
AS SOON AS POSS. CNTCT LENSES SHOULD NEVER BE WORN WHEN WORKING
W/THIS CHEM . SKIN:FLUSH AREA OF CNTCT IMMED W/LG AMTS OF WATER FOR
AT LST 15 WHILE REMOVING CONTAMD CLTHG. IF IRRIT PERSISTS AFTER
FLUSHING, GET MED ATTN PROMPTLY. WASH CLTHG BEFORE REUSE.
INHAL:IMMED (ING 13)

Flash Point Method:SCC
Flash Point:246F,119C
Lower Limits:3.2%
Extinguishing Media:H*2O FOG/FINE SPRAY. ALCOHOL RESIST FOAMS(ATC TYPE)
PREF. GEN PURPOSE SYNTHETIC FOAMS(INCL AFFF)/PROTEIN FOAMS (SUPDAT)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT INCLUDES HELMET, COAT, PANTS, BOOTS & GLOVES.
Unusual Fire/Explosion Hazard:NO FIRE & EXPLO HAZS EXPECTED UNDER NORM
STOR & HNDLG CNDTNS(IE AMBIENT TEMPS). HOWEVER, ETHYLENE
GLYCOL/ETHYLENE GLYCOL & H*2O SOLNS CAN FORM FLAM VAPS(SUPDAT)

Spill Release Procedures:SM SPILLS:SOAK UP W/ABSORB MATL. LG
SPILLS:DIKE & PUMP INTO SUITABLE CNTNRS FOR DISP. ENSURE COMPLIANCE
W/ALL APPLIC STATUTES THAT REQ NOTIFICATION OF APPROP GOVT
OFFICIALS. MATL IS MOD TOX WHEN INGES T. TAKE ADEQ PRECS TO KEEP
PEOPLE, ESP (ING 16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PRODUCT ON SURFACES CAN CAUSE SLIPPERY
CONDITIONS. PRACTICE REASONABLE CARE AND CLEANLINESS.
Other Precautions:AVOID BREATHING SPRAY MISTS IF GENERATED. KEEP OUT OF
REACH OF CHILDREN. PRODUCT MAY BECOME A SOLID AT TEMPERATURES BELOW
22C(-8F). DO NOT STORE NEAR FOOD, FOODSTUFFS, DRUGS OR POTABLE
WATER SUPPLIES.

Respiratory Protection:NIOSH APPRVD RESP PROT REQD IF AIRBORNE CONC
EXCEEDS TLV. AT ANY DETECTABLE CONC, ANY SCBA W/FULL FACEPIECE &
OPERATED IN PRESS-DEMAND OR OTHER POS PRESS MODE OR ANY
SUPPLIED-AIR RESP W/FULL FACEPIECE & OPERATED IN PRESS-DEMAND OR
(ING 18)
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:PROT GLOVES: POLYETHYLENE, (ING 21)
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING
WITH THIS CHEMICAL.
Supplemental Safety and Health
EXTING MEDIA: MAY FUNC BUT MUCH LESS EFTIVELY. CO. DRY CHEM. DO NOT USE
DIRECT H*2O STREAM. MAY SPREAD FIRE. EXPLO HAZ: W/AIR IF HEATED
SUFFICIENTLY. KEEP PEOPLE AWAY. ISOLATE AREA & DENY UNNEC ENTRY.
HAZ DECOMP:OR IF HEATED TO VERY HIGH TEMPS BY HOT WIRE/PLATE, CO &
OTHER HAZ CMPDS SUCH AS ALDEHYDES MAY BE GENERATED.

Boiling Pt:B.P. Text:>340F,>171C
Melt/Freeze Pt:M.P/F.P Text:-8F,-22C
Vapor Pres:<0.1
Vapor Density:2.1
Spec Gravity:1.12 (H*2O=1)
Evaporation Rate & Reference:NIL (BUAC=1)
Solubility in Water:COMPLETE
Appearance and Odor:GREEN; MILD ODOR.
Percent Volatiles by Volume:97

Stability Indicator/Materials to Avoid:YES
ISOLATE FROM STRONG OXIDIZERS SUCH AS PERMANGANATES, CHROMATES AND
PEROXIDES.
Stability Condition to Avoid:ISOLATE FROM OXIDIZERS, HEAT AND OPEN
FLAMES.
Hazardous Decomposition Products:HAZ COMBUST PRODS MAY INCL CO, CO*2 &
TRACE AMTS OF ALDEHYDES & ORG ACIDS. WHEN AVAIL O*2 IS LIMITED, AS
IN FIRE(SUPDAT)

Waste Disposal Methods:DO NOT DISCHARGE TO SEWER. WEAR APPROPRIATE
PERSONAL PROTECTION. TAKE UP WITH SAND, VERMICULITE OR SIMILAR
INERT MATERIAL. DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.